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allstardentist
07-26-2006, 07:33 PM
Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2

Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2

anyone?

DMD to Be
07-26-2006, 07:49 PM
Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2

Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2

anyone?

CH3 and NH2 are activators - meaning they push electrons into the ring. A, B, and C are the only deactivators. I'd probably say Bromine would have the greatest electron-withdrawing effect. Not totally sure about that though.

Immuno-guy
07-26-2006, 07:52 PM
Surely it is fluorine.

NH3 and CH3 are electron donating; leaving only halogens. Of these, F is clearly the most electonegative and therefore withdrawing.

Do we agree?

aranjuez
07-26-2006, 07:53 PM
Immuno,

Agreed.

aranjuez

allstardentist
07-26-2006, 08:04 PM
oops, u guys are right. i was right too. i just looked at the wrong solution.

DMD to Be
07-26-2006, 08:12 PM
lol, guess i'll be moving my DAT test date back a few weeks... :laugh:

dental#1
07-26-2006, 09:11 PM
Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2

Which of the following substituents has the greatest
electron-withdrawing effect?
A. Br
B. Cl
C. F
D. CH3
E. NH2




anyone?


C is 200% correct! F- is much more electronegative therefore giving it the ability to withdraw e- more than the others!(Br an Cl)
:thumbup: