View Full Version : Orgo question


Ferdowsi
07-21-2008, 06:33 PM
I have a question regarding Friedel crafts alkylation. does rearrangement occur?

Thanks

wifi08
07-21-2008, 06:37 PM
if your adding a straight chain alkane, if you have more than two methyl groups rearrangement will occur

Orgodox
07-21-2008, 06:44 PM
Yup but thats why you can do a friedel-acylation craft followed by reduction to get your straight chain on without rearrangement.

Ferdowsi
07-21-2008, 06:53 PM
Thanks guys.

topdent1
07-21-2008, 06:56 PM
I believe destroyer says that if your alkane is more than 3 carbons long, than it will rearrange to form the most stable carbocation.