View Full Version : chem "?" on destroyer.. i dont get it


Dentista08
07-26-2008, 01:07 PM
Choose the CORRECT expression for equilibrium constant, K, of the following reaction at constant temperature and pressure. 3 Fe(s) + 4 H2O(g) « Fe3O4(s) + 4 H2 (g)


A.K = [Fe3O4][H2]4 / [Fe]3[H2O]4B.K = [Fe3O4][H2]4 / [H2O]4C.K = [H2]4 / [Fe]3[H2O]4D.K = [H2]4 / [H2O]4E.K = [Fe3O4] / [Fe]3
I cant understand why its not a?? the explanation says that Fe..etc are pure solids are constant values encorporated into Keq? It just doesn't make sense to me.. :(
Thanks :)

Thundercatz
07-26-2008, 01:12 PM
Its not A because you dont include solids in the expression.

Dentista08
07-26-2008, 01:16 PM
than you for the reply=) but the explanation says pure solids or liquids? I would think water is a pure liquid? Or does it mean that if it's composed with more than 1 atom, it's not pure anymore?

cherr1pop
07-26-2008, 01:19 PM
it says H2O(g) so it's a gas for that reaction.

Thundercatz
07-26-2008, 01:25 PM
than you for the reply=) but the explanation says pure solids or liquids? I would think water is a pure liquid? Or does it mean that if it's composed with more than 1 atom, it's not pure anymore?


Yea, H2O is listed as a gas in that expression...hehe

zDDS
07-26-2008, 01:32 PM
i believe when calculating equilibrium YOU DONT USE SOLIDs (s)

MattEvers
07-26-2008, 01:40 PM
The concentrations of liquids and solids do not change, therefore they can be left out of the equilibrium equation.

Dentista08
07-26-2008, 01:55 PM
thanks everyone! Now i get it :) For some reason, equillibrium is my worst topic.. even though i know it should be easy!!!