Do triprotic titrations have a 3rd equivalence point?

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stester77s

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I'm searching a lot of triprotic titrations such as this one: https://www.google.com/search?q=tri...edu%2F~toh%2Fmodels%2FTitration.html;1094;543


And the triprotic titrations look a lot like diprotic titrations... i.e. there is no third equivalence point. Why is this? Do triprotic titrations sometimes have a third equivalence point and sometimes not? Why is that?

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It does, it is just barely noticeable because of how weak of a pKa value it has.
 
^^Ditto. the 1st Eq pt, H2A dominates, then the 2nd eq. point, HA dominates...then the last eq. pt, A- (all deprotonated) dominates...
#of protons is typically indicative of the number of eq. pts.
 
Does this mean that the pkb is really strong for the third proton to remove or first proton to be added? For example co2 would have a really high tendency and a low pkb to turn into hco3 right? But a low tendency to become co2 from hco3
 
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