My guess: organic liquid most likely to have higher MW than water therefore they'll have higher b.p. Or you can look at this way: more solute in organic liquid = higher b.p
is it a solution containing an organic liquid or a pure sample of the organic liquid?
Labrat07 is right that organic liquids containing H, C and O or another heteroatom will have higher bps than water, but a lot of the shorter chain alkanes have a bp lower than 100 degrees.
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