I'd say that you're slightly confused.
For example, either methanol or ethanol, I can't remember, has a boiling point of about 78C. Water tends to (unless you add a lot of stuff to it) have a boiling point of 100.
Generally, the larger (and more branched) the molecule is, the higher the boiling point, as hydrogen bonding from the -OH is replaced by a much stronger force -- london forces. With large molecules comes a mass of electrons, and small branched molecules allow them to pack closer together.