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I mean, I don't know your confidence level w/ the Gen Chem material but I guarantee you that the people who are going to be in Orgo first semester will be the gunners who don't know any better (i.e. they don't know that they probably should have taken Gen Chem again).But then how big of a difference is it taking Gen Chem and Orgo if I'll be stuck in Gen Chem with a boatload of other kids who got 5's on the exam?
I would liken it to, say, being in a 10k versus your first half marathon. Even if you're doing the 10k with a lot of people who already did 10k's in the past, at the very worst you'll end up at the front of the pack past the people who have never run a race before (i.e. people who didn't take AP). If you take the marathon, though, you're only familiar with the beginning 6.2 miles but then you quickly realize that its more than you anticipated.