Before 2003, alkene and benzene chemistry was tested. For some reason, they removed those when they reformatted the MCAT in 2003 (used to be VR 65 que first, PS 77 que second, 2 essays, and then BS 77 que).
Alkyne reactions have never been tested, although the acidity of a terminal alkyne and it's utitlity as a nucleophile in an SN2 reaction is fair game.
Elimination is still a topic as far as I know (it's on their list and they have asked about it before... a search here will show this). Also, diene addition (1,2 vs. 1,4) is a fair subject for some reason, so additions to pi-bonds is a potential topic.
If you ask me, the test writers just write whatever the heck they want and AAMC doesn't check to see whether if it meets their criteria from the topic list. I might be wrong.