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- Jul 18, 2010
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Reaction 1: CH4 + OH --> CH3 + H2O
Reaction (1) is exothermic because:
A.
the C–H σ bond is stronger than the O–H σ bond.
B.
the C–H σ bond is weaker than the O–H σ bond.
Correct Answer
C.
the C–H σ bond is stronger than the O–H π bond.
D.
the C–H σ bond is weaker than the O–H π bond.
Explanation:
B. There is a single sigma bond between the H and O (choices C and D are eliminated). Recall that ΔH = Hproducts – Hreactants. In order for the reaction to be exothermic (negative ΔH), Hreactants must be greater than Hproducts. The H of a molecule is the sum of the bond energies. Watch out, though, because you have to remember that bond strength is inversely related to bond energy! So the bond strength of the reactants have to be less than that of the products (choice B).
I don't understand why they said bond strength is inversely related to bond energy. I thought it was a direct relationship. Can someone please explain?
Reaction (1) is exothermic because:
the C–H σ bond is stronger than the O–H σ bond.
the C–H σ bond is weaker than the O–H σ bond.
Correct Answer
the C–H σ bond is stronger than the O–H π bond.
the C–H σ bond is weaker than the O–H π bond.
Explanation:
B. There is a single sigma bond between the H and O (choices C and D are eliminated). Recall that ΔH = Hproducts – Hreactants. In order for the reaction to be exothermic (negative ΔH), Hreactants must be greater than Hproducts. The H of a molecule is the sum of the bond energies. Watch out, though, because you have to remember that bond strength is inversely related to bond energy! So the bond strength of the reactants have to be less than that of the products (choice B).
I don't understand why they said bond strength is inversely related to bond energy. I thought it was a direct relationship. Can someone please explain?