Learn how electrons flow, who dances with who. Why does a particular type of molecule break apart during an organic reaction vs. another. Why won't an SN1 work for one reaction and will for another?
Part of that is memorization and part of that is just doing problems and understanding the chemistry behind it all.
I memorized the alcohols (primary, tertiary; reagents, etc) and what removed them via which mechanism, and I did ALL the suggested homework problems. In addition, because I'm not spatially oriented, I did buy the full blown molecule kit so I could see how impossible a reaction might be due to the structure of the original substrates themselves.
ALL those bond angles, for me, were easier to understand by building the molecule. But, everyone learns differently.
My first orgo exam was all the ketone v aldehyde v alcohol v imine v amine v .... and the basics. the next exam was more mechanisms on SN1, SN2, E1, E2; the 3rd was synthesis... the final was cumulative. I A'd the first, B'd the next 2, and A'd the final (125 points on 100 point test because I nailed the synthesis in less than 10 steps).