Carbonate Buffer Question and Ocean acidification

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Bleepbloopblop

Full Member
7+ Year Member
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Hey,

I am a little confused about the mechanisms of ocean acidification and carbonate buffer system. So I understand an increase in CO2 will react with H2O to form H2CO3.

H2CO3 --> H + + HCO3 - --> H+ + CO3 2-

And sea creatures use CO3 2- to form Ca2+(Co3-). However, i know that Ocean acidification reduces the amount of CO3 2- by reacting with excess hydronium ions to form more bicarbonate ions.

My question is, if CO2 increases, therefore increasing H2CO3, H+, and HCO3-, shouldn't the increase in HCO3- cause the equilibrium to shift to the right forming more CO3 2-? Why does it instead cause Carbonate ion concentration to drop?

Thanks so much for any help.