I believe you would take the antisine of (1/1.5) to get theta. which is antisine (2/3) so.
antisine(.6 )ends up at an angle between 30 and 45 right?
Basically n1sin(theta1)= n2sin(theta2) assuming that n1 is the less dense material and n2 is the more dense material. Set theta 1= 90deg. because the critical angle is the angle at which light is refracted along the surface of a medium. The angle of refraction is going to be 90 degrees (reflected perpendicularly to the normal) sin90 is 1. Then solve for theta2, to get the critical angle the angle at which the incident light ray mus strike to cause a 90degree angle of refraction.
If that explanation doesn't make sense (and it wouldn't to me. I think you have to see it) look at this:
http://hyperphysics.phy-astr.gsu.edu/hbase/phyopt/totint.html