Destroyer Ochem Question

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dentalduck15

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Q: given two compounds (toluene and C2H5-O-C2H5) How would you seperate these two compounds?
Answer Choices: NMR Spec, Acid/Base extraction, Simple Distillation, Combustion Analysis,or IR Spec?

Thanks for all the help guys.
 
Simple distillation. Differences in boiling points would lead you to this answer. The only other possible answer for separating compounds is acid-base extraction and this wouldn't work. The other three won't separate compounds.