One way I think of it when I want a general answer (greater/less than/equal to fs) is to imagine the waves being emitted with respect to if the source/observer are converging or diverging.
In this problem, the bus and the biker are diverging, or getting farther apart (25m/s > 5m/s). The waves continually need to travel a greater and greater distance to go from source to observer. Longer time between cycles/waves, or in other words, less frequent waves/cycles means that frequency decreases compared to if the distance between the two objects were constant. Or in other words, the perceived frequency should be less than the actual frequency.
In this question then, A and B would be ruled out, and from experience or by looking at the formula for a bit, you know you would need very extreme conditions for about a 2-fold change in frequency, so D is very unlikely. Thus, you would choose C.