So, to understand why these two equations look similar, we need to see how potential energy is related to force.
Force = k (q)(q)/ (r^2). Remember that force is a vector.
Based on this, we get the electric field by dividing by the charge:
Electric field = k(q)(q)/(r^2). This is also a vector.
However, to get from electric field to electric potential, the actual derivation requires calculus , which you DONT NEED TO KNOW for the MCAT. Anway we get:
Electric Potential = k(q)/(r). Note, this is a scalar value!
Lastly, electric potential energy is just electric potential * charge, so we get:
Electric potential energy = q*V = k(q)(q) / (r). This is also a scalar.
If you want to know why there is an r on the bottom instead of an r^2 look up the derivation of electric potential from electric field, but know that you DONT NEED TO KNOW IT FOR THE MCAT (the derivation that is). You just need to know how to use the equations.