All carbonate salts are insoluble except for the group 1 akali metals. While Li is much less soluble than say Na or K....Li2CO3 should dissociate in water. The # of particles would be 3 (2 Li ions + 1 CO3 ion). Someone with more recent/better chemistry background can double check me on that. It would make the solution more hypertonic...as you now have more solutes, 3 ions, versus the 1 molecule before Li2CO3 disassociated.