According to the following reaction,
2 Ag+ + S2- à Ag2S
1) Determine the Limiting Reactant (LR):
1 mol Ag+ x (1 mol S2- / 2 mol Ag+ ) = 0.5 mol of S2- are required for the reaction to occur, but since theres 4 mol of S2- present, the excess reactant is S2-, which makes Ag+ the LR.
2) Use the LR to find the amount of product formed (Ag2S):
1 mol Ag+ x ( 1 mol Ag2S / 2 mol Ag+ ) = 0.5 mol Ag2S is formed
3) Find the amount of excess reactant used:
0.5 mol Ag2S x ( 1 mol S2- / 1 mol Ag2S ) = 0.5 mol of S2- are used up in the reaction.
4) The amount of Sulfide remaining = original amount of S2- -- amount of S2- used up
Amt of sulfide remaining = 4 mol S2- -- 0.5 mol S2- = 3.5 mol of S2- remaining
Summary:
a) The excess reactant is S2-
b) Amt of sulfide remaining = 3.5 mol of S2- remaining