I have read that the addition of an inert gas to an equilibrium reaction held at a constant volume exerts no effect on the equilibrium. I would think that by adding another gas (i.e., to a mixture of gases), even if it is inert and non-reactive, would increase the overall pressure of the system. An increase in the system's pressure would then cause the equilibrium to shift in the direction with fewer gas molecules (assuming there are unequal numbers of molecules on each side of the reaction). Can somebody clear this up for me?