During systole, the ventricles contract to send blood to the lungs and body and during diastole the atria contract to fill the ventricles with blood. You wouldn't want the ventricles and atria to contract together because that would prevent efficient pumping.
I remember the common "120/80 mmHg" bp reading knowing that systole is the top number- it's the higher number because you need more pressure to pump blood to the whole body.