Are you talking about vent weaning in the OR for a patient under GA? Or about ICU ventilator weaning where we have patients who are essentially awake and triggering the ventilator?
Keep in mind, we don't use A/C in the OR. That's an ICU ventilator mode that can be either pressure or volume controlled. The RR on A/C is essentially a minmim or backup. The vent will assist by delivering a set pressure or volume at the minimum set RR, or if the patient is breathing (triggering), deliver said Vt or P with each triggered breath. If a patient is breathing at a rate of 18 and the RR set on the vent is 15, you can drop the RR to 4 or whatever you like, but the patient will get the 18 breaths he is triggering.
PSV is nice because it slowly shifts the work of breathing to the patient. It's nice in the OR because often you can set a backup RR, or add the mode into your control mode (Draeger Apollo), and slowly shift a patient to PSV and wean to SV/extubation at end of the case. You lower the RR on a controlled mode in the OR under GA because you want to build co2 and get the patient to breathe on their own. You can do this by lowering Vt too. Changing peep doesn't truly wean a patient because peep won't drive their own spontaneous respiration; it's more to maintain oxygenation.
Hope this helps. There are other parameters you can play with in either mode (inspiratory times, flow vs pressure triggers, changing the peak flow rate at which PSV cycles to exhalation, etc) if you really wanna be precise, but often that's unnecessary in the OR.