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Thoughts on this?
I thought PS harder than usual...
I thought PS harder than usual...
DieselPetrolGrl said:ochem was a doozie its nothing like class
its all about O18 nudging its way into things ( i got that Q wrong)
its like u haveto inutuition the mechanism to get it right
ExplodingBoy said:that one was actually not too bad i thought, as long as you understand whats happening. The O18 wasnt replacing any other O's, or pushing them out, it was just making an ether bond, so thats why it appears in the final molecule. =)
Hope the explanation helps a bit. Now the (+)- B-elemene.... I didn't get that at all.... why is (+)- the enantiomer of (-)- and not just a diastereomer? There were 3 chiral centers, so I thought since one of the signs were changing, only one of the centers would.
docjolly said:Well, ExplodingBoy,
the +/- signs represent the fact that enantiomers, not diasteromers, can rotate plan polarized light. This is the only was to differentiate between enantiomers b/c they have the same physical properties (and I believe the majority of their chemical properties are the same) . Diastereomers, on the other hand, have different physical properties, and hence, can be separated by physical means..
Anyhow, so, since there are 3 chiral centers for the (-) Beta elemene, the 3 stereocenters of its enantiomer (the (+) Beta elemene) MUST ALL BE INVERTED (so that they will be enantiomers). I hope this makes some sense..