Alpha/Beta sugars

This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.

Sammy1024

Full Member
7+ Year Member
Joined
Dec 12, 2013
Messages
701
Reaction score
59
So I was wondering how you could count the carbons on a sugar ring? I always count from the O CW but a questions I did counted them both directions.

Also does cis/trans connection affect the type of bonding (Alpha vs. Beta)?

upload_2014-8-9_7-47-27.png


I thought these were two alpha connections but it was alpha beta

Also I don't see how this is an acetal bond.

upload_2014-8-9_7-54-24.png


I can see the O and the second sugar as being the OR, but where is the other OR?

Members don't see this ad.
 
Last edited:
For alpha and beta. I remember this acronym AtBc. This means alpha anomer oxygen is trans to CH2OH and beta is cis to it.
For counting hexoses, I think it is simpler to remember that C-5 doesn't have a -OH group but is only attached to the CH2OH group, this is true for both furanoses and pyranoses

The other R is the first sugar. Sugar - O - Sugar = R-O-R
 
Top