Amines, amides, imines, enamines....

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JSW8405

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Does anyone know a helpful mnemonic for remembering the structures of these things? I always get them mixed up, especially under pressure.

Thanks

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i dunno an mnemonic, but to remember imine/enamine, just think of it as analogous to keto/enol of a carbonyl.

An imine is a like the keto form, except the oxygen is replaced by a nitrogen.

An enamine is like the enol form, except the oxygen is replaced by a nitrogen.

(In fact, imine and enamine tautomerize just like keto/enol)

Amide, just think of amino acid peptide bonds.

Amines are just like ammonia with stuff (hydrogens) replaced by carbons.
 
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