The only time ochm really helps biochm make sense is when you have a much much much advanced level of ochem.
QofQuimica was once telling us (in a thread on the MCAT forum) that her advanced training in a Chem PhD made biochem in med school easier because she could figure out the pathways mechanistically.
However, at the intro level you don't really learn so deep or have the time to learn the pathways that deep to the point of knowing the intricacies of the pathway mechanisms.
In most general biochem classes people tend to do a lot more memorization of the pathways by drawing it out over and over again on paper or white boards til they have it down.
The extent of application in pathways is generally in relation to labelling carbons and tracing the pathway of a carbon throughout the pathway.
For instance, you have a glucose molecule undergoing glycolysis and are asked to figure out the fate of the C1 carbon of the glucose molecule.
however, that does not need every detailed amt of ochem. But again I repeat Biochem is what you get when you mesh parts of ochm, parts of inorganic chm, parts of physical chm, parts of bio and especially molecular/cellular biology, and mesh it all together.