Prior to DNA replication (S phase), our cells contain 46 chromosomes. During S phase, all 46 chromosomes are copied, and because they are identical copies, it is accurate to say that there are now 92 (46 + 46) chromosomes in the nucleus.
But, "chromatid" is a term used to describe them until the completion of cell division. A chromatid is just what you would call a chromosome during mitosis. In addition, the chromatids are stuck together after S phase, so we could also say that there are 46 pairs of chromatids (or chromosomes) at the end of S phase, and be no less accurate. Once the (autosomal) cell goes through mitosis, these 46 pairs will separate into 2 identical daughter cells, each with 46 chromosomes.