Destroyer Chem #87

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JNew

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Don't really understand why if Kw got smaller, the reaction must be endothermic. Anybody?
 
Don't really understand why if Kw got smaller, the reaction must be endothermic. Anybody?

We consider "heat" as a part of reactants. Since we're decreasing the temperature, this equivalents to removing heat from reactants. By Le Chatelier's Principle, rxn favors the formation of reactants b/c heat is removed, so Kw decreases.
 
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