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TBR Gen Chem: Ch. 7, Passage 11 , #76
Which of the following liquids would form the DENSEST vapor upon heating?
A. CH3CH2CH2OH
B. CH3(CH2)3CH2Cl
C. CH3(CH2)4CH2Br
D. (CH3)3CCH2OH
Given the passage is about real gasses.... wouldn't attractive forces of alcohols be dominant effect here? I know hydrogen bonding is more of a liquid/solid property but if the a value in van der waals equation is squared... why wouldn't H-bond like attractions be noticable? And how could we say that molecular mass (induced dipole/london dispersion effects) is more important?!
The answer is C because it has the highest molecular mass but I don't understand why molecular mass beats out H-bond attractions here.
Which of the following liquids would form the DENSEST vapor upon heating?
A. CH3CH2CH2OH
B. CH3(CH2)3CH2Cl
C. CH3(CH2)4CH2Br
D. (CH3)3CCH2OH
Given the passage is about real gasses.... wouldn't attractive forces of alcohols be dominant effect here? I know hydrogen bonding is more of a liquid/solid property but if the a value in van der waals equation is squared... why wouldn't H-bond like attractions be noticable? And how could we say that molecular mass (induced dipole/london dispersion effects) is more important?!
The answer is C because it has the highest molecular mass but I don't understand why molecular mass beats out H-bond attractions here.