Gen Chem Question

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Metswin677

Full Member
10+ Year Member
I have a question.....

A compound contains 27.3% carbon, and 72.7% oxygen by mass. What is the expirical formula....When I try this, I divide 72.7/27.3 and I get C:O ration of 1:2.66

The answer from Collins is CO2.....why is it not CO3?
 
Hi,

You need to divide both C and O by their atomic weight, so for C, 27/2= ~2

and for O, 72/16= ~4, and you get the molecular formula C2O4, and the empirical formula would be CO2. Hope that makes sense.
 
Hi,

You need to divide both C and O by their atomic weight, so for C, 27/2= ~2

and for O, 72/16= ~4, and you get the molecular formula C2O4, and the empirical formula would be CO2. Hope that makes sense.

I thought you stay consistent and divide both sides by the lowest molecular weight. Guess not....
 
First, get the moles for both C and O.
Divide 27.3 by the Molarity of C : 27.3/12 = 2.275
Divide 72.12 by the molarity of O: 72.7/16 = 4.54

Then, get all the numbers of moles divided by the smallest number of mole.

For C, 2.275/2.275=1
For O, 4.54/2.275 =~ 2

So you can get the empirical formula for this: CO2.
Hope this helps.
 
Last edited:
First, get the moles for both C and O.
Divide 27.3 by the Molarity of C : 27.3/12 = 2.275
Divide 72.12 by the molarity of O: 72.7/16 = 4.54

Then, get all the numbers of moles divided by the smallest number of mole.

For C, 2.275/2.275=1
For O, 4.54/2.275 =~ 2

So you can get the empirical formula for this: CO2.
Hope this helps.

Thanks Alot...Looks good!