How is n=3 holding 18 e-?

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prsndwg

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Is it b/c of the 3d sub shells? if yes, Why do we count them? shoudnt they be counted for n=4??
I am confused!!
 
a simple formula to find the maximum number of electrons with a given principal quantum number, n, is 2n^2.

in your case, n=3, so 2n^2 is 18 e-.

if you write out the values for the other quantum numbers for n=3, you get:

l= 0, 1, 2 (these correspond to the s, p, d subshells, respectively)
ml= 0
-1, 0, 1
-2, -1, 0, 1, 2

these ml values represent the number of orbitals you have, and there are two electrons that can occupy each orbital. so you have 9 total orbitals times 2 electrons each, and you have 18 total.
 
Thank you..
Is my reasoning that 3d subshell would be counted it wrong?
 
You're reasoning would have been right, but you forgot that the d subshell has an L value of 2, and L values exist from 0 to n-1 (n being 3 in this case). Another way to do it is draw that "step" diagram with all the orbitals and arrows to illustrate Aufbau's Principle.
 
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