When you take the real MCAT, you are not expected to know molecular weights off the top of your head. Click the "Exhibit" button to open the periodic table and calculate them that way. While studying, I would encourage you to leave a periodic table handy but not leave it out in front of you so you will force yourself to remember to get the periodic table when you need it.
It doesn't hurt to have a few elemental molecular weights off the top of your head however... CO2 = 44, N2 = 28, O2 = 32, H2O = 18, NH3 = 17, etc. Small molecules aren't too bad to remember as you are likely doing the calculation quickly in your head from atomic weights of C = 12, N = 14, O = 16, and H = 1.
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