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0.1 moles of an ideal gas with Cv = 3R/2, initially confined to a container of volume 3 litre and at a temperature 6 C, expand (or are compressed) against a constant external pressure of 0.8 atm until the final pressure of the gas is equal to the external pressure and the final temperature of the gas is equal to the temperature of the surroundings. During this process the system does 4,354 J of work on the surroundings. Calculate the change in entropy, Delta S, of the gas (in J / K).
I first calculated P1 by equating it to nRT1/V1.
Then I calculated V2 by using w = -Pext (Vf-Vi)
Then I calculated T2 by using T2 = P2V2/nR
Then I used the formula
Delta S = n Cv ln(T2/T1) + nR ln (V2/V1)
and plugged in the numbers to get 15.848
However, the correct answer is 6.2, which is just the latter portion of the Delta S equation "nR ln (V2/V1)".
I am wondering why you discard the former part of the Delta S equation "n Cv ln(T2/T1)"... Does that mean the two temperatures are somehow equal?
Please enlighten me as to what I did wrong. thank you!!
I first calculated P1 by equating it to nRT1/V1.
Then I calculated V2 by using w = -Pext (Vf-Vi)
Then I calculated T2 by using T2 = P2V2/nR
Then I used the formula
Delta S = n Cv ln(T2/T1) + nR ln (V2/V1)
and plugged in the numbers to get 15.848
However, the correct answer is 6.2, which is just the latter portion of the Delta S equation "nR ln (V2/V1)".
I am wondering why you discard the former part of the Delta S equation "n Cv ln(T2/T1)"... Does that mean the two temperatures are somehow equal?
Please enlighten me as to what I did wrong. thank you!!