Nmr

This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.
Downfield (to the left) is in the direction of low magnetic field strength. Substitutions, such as an oxygen atom in an aldehyde withdraws electrons, thereby decreasing the shielding of the protons by electrons. In this case you need a lower magnetic field (downfield) to make the protons absorb EM energy from a constant strength magnetic field.
However substitutents, such as a methyl group donates electrons, which shields the protons, and in this case you need a stronger magnetic field, upfield, to the right.
 
Downfield (to the left) is in the direction of low magnetic field strength. Substitutions, such as an oxygen atom in an aldehyde withdraws electrons, thereby decreasing the shielding of the protons by electrons. In this case you need a lower magnetic field (downfield) to make the protons absorb EM energy from a constant strength magnetic field.
However substitutents, such as a methyl group donates electrons, which shields the protons, and in this case you need a stronger magnetic field, upfield, to the right.
3° hydrogens are more downfield (deshielded) than 2° hydrogens.
 

Similar threads

D
  • Question Question
Replies
1
Views
1K
6
  • Question Question
Replies
18
Views
4K
D
  • Question Question
Replies
6
Views
990
deleted647690
D
6
Replies
21
Views
5K
Top