do a search on SDN for the military thing - it has been discussed before. It is not a straight forward yes or no. you can also call the different branches of the military to ask how it works for podiatry. I do not think it is as good as what is offered to the MDs/DOs.
For NYCPM you'll need to rent or buy a microscope for the 1st year. By the end of the 1st or 2nd year you'll need an opthalmascope, stethescope, blood pressure cuff, reflex hammer, tunning forks, and other little things for physiology lab and physical assessment. All of which is sold or rented in the school store at NYCPM. or you can search for better deals.
You are provided with your first white coat free in September of the 1st year.
For Anatomy lab you'll need a disecting kit and gloves. You'll also need to purchase scrubs unless you have them already.