Periodic table trends - electron affinity

This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.
Get help with your application

Use all the free resources available to you from SDN: articles, guides, expert advising, forums discussions, and school research.

CaptainAmazon

Full Member
Advertisement - Members don't see this ad
I have had good luck with understanding the trends as opposed to memorizing them, but the only one that hasn't clicked is electron affinity. Why would having a greater electrostatic pull from the nucleus (Zeff) cause an element to dissipate more energy as it gains an electron (e- affinity increases)? I can't seem to picture this, so any help would be appreciated.
 
Think about before and after. Before, the electron is just meandering around aimlessly. After, it's in a very happy and stable place if the nucleus has a strong attraction for it and a shell gets filled when it adds. The better the "after", the more energy it releases as it relaxes to a highly stable ("after") state.

The thing that messed with me was the sign convention.