Here you go,
Let the average be x, so the 6th person spends x+5
Now Average = Total / N
x = (5(16)+x+5)/6
Since 5 people spend 16 each, their total will be 5(16)
Now solve for x,
x = 80+x+5/6
6x = 85+x
x = 17
Remember, the sixth person spend x+5 = 17+5 = 22