Question about color--absorption and emission

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dxu425

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I'm getting pretty confused about light and color and making the distinction between reflected light and emitted (?) light. There are two questions in the TPR Workbook, Gen Chem section:

1) A blue transition metal complex absorbs photons of what color?
The correct answer is orange. So this complex is blue because it is maximally absorbing the wavelength of the complementary color, orange, right?

2) Sodium-vapor street lights are bright yellow. This means the majority of photons being emitted by the lamps are:
The correct answer is yellow. So compounds that emit photons of a certain wavelength will be that color?

When I'm doing these problems, should I make the distinction between absorption vs. emission? And is fluorescence, when electrons absorb a certain amount of energy and are excited to a higher state, then fall back to a lower state and in the process emit a photon, then related to the concept of emission? So fluorescent compounds are the color of the photon they emit?

Thank you!!

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Yes, you have to account for absorption/emission. An easy way to figure out if you have a case of absorption or emission is to ask yourself: If I had this object in a completely dark room, would I see it? If the answer is yes, the object is emitting light and its color will be the color that you observe. If the answer is no, the object is only reflecting light and absorbing some wavelengths. The colors that you observe will be the ones that were not absorbed, so if you see a certain the color, it is its complement that is being absorbed.
 
It sounds like you have the basics.

Absorption REMOVES colors, leaving the complimentary color.

Emission ADDS colors, enriching the colors that your see by that light.

You also need to consider if more than one wavelength is being emitted or absorbed, and that PIGMENTS are different than LIGHT.

With LIGHT the primary colors are blue, red and green.
Secondary colors are yellow = red and green, cyan (sky blue) = green and blue, magenta (purple) = red and blue.
Tertiary colors (all three mixed together) = WHITE

With PIGMENTS, the primary colors are cyan, magenta and yellow.
secondary colors are red = magenta + yellow. green = yellow + cyan. and blue = magenta + cyan.
Tertiary color of pigments = black.

dsoz
 
ROYGBV
little trick line complementry colors them on top of each other
ROY
GBV
Eg: orange and blue are complementary colors, the removal of blue from a white light looks orange
 
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