In order to get the electrons to cancel out, you have to multiply the second equation(the Sn one) by 3, cause you have to add 6 electrons to the reactant side of the Cr2O7 equation.
In order to get the electrons to cancel out, you have to multiply the second equation(the Sn one) by 3, cause you have to add 6 electrons to the reactant side of the Cr2O7 equation.
If you break apart the original redox eq into its two respective parts(the Cr2O7-->Cr+3 and then the Sn one) and then balance them both individually, you will see that you add 6 electrons to the reactants side of the Cr2O7 equation, and 2 electrons to the product side of the Sn equation. In order to cancel electrons you have to make them equal, so you multiply the second(Sn) equation by 3, cause 2X3=6, so then you can cancel out those electrons. Thats why you have the 3 in front of the Sn.
Sn +2...............Sn+4 (-2 e)
Cr2O7 -2.......... Cr+3
(+6................+3) (+3e)
Need to balance loss and gain of electrons. Therefore multiply (-2e)x 3 and (+3e) x 2.