Adding another capacitor in series will decrease the equivalent capacitance. The starting current is E/R and will stay the same. The decay is e^(-t/RC). If you decrease C, t/RC will increase and -t/RC will decrease. The graph will get squished towards the horizontal axis and will approach it faster. It's the opposite of what happens when you add a capacitor in parallel. Note that the graph will not exactly shrink, in a sense that the point where it crosses the y axis will stay the same.