1. You don't have to memorize any reagents for the MCAT as far as I know
2. You should be familiar with alkene/alkyne reactions from your organic chemistry class anyways, so just review them
3. Alkyne weren't in TBR o-chem which is pretty dang detailed so I think you'll be okay.
4. But for alkenes, you should understand the basic mechanism behind SN1/SN2/E1/E2 and what conditions favors each, and what determines rate of rxn(electrophile only for SN1, nucleophile + electrophile for SN2, strong acid for E1, strong base for E2, carbocation intermediate in E1/SN1, concerted E2/SN2, effects of LG/nucleophile/solvent/other substituents that may influence the basicity of the LG and stability of the electrophilic carbon)
I don't know if you really have to memorize what conditions favors what, but going in overprepared is better than under.