Titrations question

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joescollegiate

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While reviewing titrations, I saw the sentence "you can only accurately titrations something from dark to colorless." Is/why is this true? In chem labs I've been in we almost always went colorless to colorful.
 
I am taking gen chem II and from what I have learned different indicators can be used for titrations..for example, phenolphthalein is a popular one that turns pink in basic solutions. As for your question, I think the statement is incorrect because indicators can change colors either way depending on if it is an acidic or basic solution...
 
I'm guessing all they mean is that dark to colorless is less subjective. Essentially it's easier to tell the difference and less risk of error. The solution either has a color or it does not. But, let's say your indicator goes from red (when basic) to yellow (when acidic). Your indicator (indi-) would be a in 1:1 ratio with H-indicator when the color is orange. But, I don't know about you, but in solution, red and orange can look pretty damn similiar. Thus, an indicator that goes from colored, to not colored makes detection much easier.

I don't know if this is what they were getting at but it was a good exercise for me anyways. My buffer and titrations knowledge needs the help.
 
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