i dont have topscore wit me at this moment, but i think it's like this:
# moles of Cl2 = PCl3 = .4(14.25)
# moles of PCl5 = .6(14.25)
To get the conc. of each one, divide them by 3 since the volume is 3L.
so Kc= (.4(14.25/3))^2/(.6*14.25/3)
I remember topscore actually multilplied out .4 *14.25/3 and .6*14.25/3