Both the s orbital and the d orbitals of the next lowest principle energy level (eg. 4s and 3d) would be part the valence shell in transition metals since the two are very similar in energy, and you'll see the ground state electron configuration of TMs as e-s in both the s and d. However, when ground state TMs lose electrons, for example, when oxidized or when forming TM coordination complexes, they'll generally lose electrons from the s orbital first, leaving electrons only in the d orbitals.