Why tertiary alcohol dehydrate the fastest?

This forum made possible through the generous support of SDN members, donors, and sponsors. Thank you.
Get help with your application

Use all the free resources available to you from SDN: articles, guides, expert advising, forums discussions, and school research.

nknhatkhanh

Full Member
10+ Year Member
Advertisement - Members don't see this ad
Why tertiary alcohol dehydrate fastest?
It is suppose to be least likely to "dehydrate" because tertiary position is the most stable place to be
 
Last edited:
Why tertiary alcohol dehydrate fastest?
It is suppose to be least likely to "dehydrate" because tertiary position is the most stable place to be

A tertiary alcohol dehydrates the most rapid indeed.

We protonate first, then form the carbocation. A tertiary carbocation is very stable, and the rate at which it forms is fast.

You seem a bit confused. When an alcohol is placed in an acidic medium such as HBr, it will protonate and lose the OH group as water.

Primary alcohols goes slowly and do not even form a carbocation !!! Secondary alcohols react fairly quick,,,,,tertiary alcohols react super fast !!!

Hope this helps.

Dr. Jim Romano