I'm assuming since you're new, you're probably floating. I'd say arrive a few minutes early and get to know layout of pharmacy and drug locations. First thing I do in the morning is clear out all data reviews...usually 10 minutes or so. When you're one tech and one RPh, the RPh does all the filling. I just let ALPS print for me. So, if I have 5 labels to fill, I go fill them place on belt and go back to data review. I look at number of F4s (data reviews to be done in next 2 hours) and I always add a couple to stay ahead or do a couple for other stores if that caught up. Then I product review. Then I'd check if there are voice mails. More labels print. Lather, rinse, repeat. When second tech comes in, I can focus solely on RPh duties. Caught up on data/product review? Start hitting the adherence calls. Do them in between tasks.
If you have a bunch of waiters and an immunization, everything will be filled in time order. I don't necessarily put an rx in front of an immunization (unless sick child, acute pain med, etc.). Complete all necessary data reviews and product reviews ahead of immunization (waiters with promise time ahead of immunization ). Make sure techs are filling waiting rxs (entered after immunization) while giving immunization. Come back and product review those. Obviously, everything depends on how good a tech you have.
Since the original topic is about pharmacist as a solo act, I'd get thru all my exceptions in the morning. Refax WCB >48 hours, Check unworked TPRs, look at DURs and MSC. Due to the volume of most WAGs, it's probably pretty rare that you'll be working a solo shift, unless it's the weekend at a brand new store or something.
I try to do as much WLB (work load balancing) as possible. I suppose I believe in karma. You can help those when help is needed, and it should help you when you're in the weeds.
Of course, you're day can be made or broken by the quality of technician you have. If you are working with a great one, thank them for their hard work after your shift. By the techs drinks or snacks.
If you have specific questions, you can always PM me or post a scenario and I'll tell you how I'd handle it.