H3PO4(s) + H2O(l) ⇌ H3O+(aq) + H2PO4–(aq) Ka1= 7.5×10−3
H3PO4 is polyprotic meaning, it has more than one proton to shed off...
H2PO4- + H2O -> H30+ + HPO4 2minus... this too can make a conjugate base: PO4-...
thus, PO4- isnt the conjugate base of H3PO4