ok this is how i look at it.... if your mom asks u how many eggs are in the frig u wont say 524.654 right? cuz that doesnt make sense. Avogadro's Number works the same way... its when you want to COUNT the number of electrons, hydrogens, OH's, C's, donkeys, monkeys, hats or whatever lol
so its for when u count and a keyword to keep in mind when u see a question is NUMBER
hope that helped