- Joined
- Dec 18, 2008
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Hey, so I am solid in oxidation and reduction reactions in ochem, but I came across one last one in my text, called the Baeyer–Villiger oxidation.
Basically its
aldehyde + peroxyacid -> carboxylic acid
and
ketone + peroxyacid -> ester
Now, you might say..big deal..just memorize it, but I have not seen it ever before and my brain feels like its about to explode as it is.
I did not think it was important but in the synthesis section at the end of the chapter its used a few times...what do you guys think? likely to appear on DAT?
Edit: Also two more quick things: 1. protecting groups? converting ketones into ketals with diols so that you can keep them intact while reacting the molecule and then converting them back into ketones
..and 2. addition of sulfur nucleophiles to ketones and being able to then reduce the C-S bonds to C-H bonds
Is all of this overkill??
Basically its
aldehyde + peroxyacid -> carboxylic acid
and
ketone + peroxyacid -> ester
Now, you might say..big deal..just memorize it, but I have not seen it ever before and my brain feels like its about to explode as it is.
I did not think it was important but in the synthesis section at the end of the chapter its used a few times...what do you guys think? likely to appear on DAT?
Edit: Also two more quick things: 1. protecting groups? converting ketones into ketals with diols so that you can keep them intact while reacting the molecule and then converting them back into ketones
..and 2. addition of sulfur nucleophiles to ketones and being able to then reduce the C-S bonds to C-H bonds
Is all of this overkill??