Given two compounds A and B and the fact that B has a higher molecular mass than A, but A is denser than B. which of the following mixtures would have the greatest mole fraction of A ?
A. Mixture of 1.0 g of compound A and 1 g of compound B
B. mixture of 1 ml compound A with 1ml compound B.
When I was doing this question, it drove me crazy. Then I figured it out. Best feeling ever.
For answer B, since A is denser than B, then you get more grams A per mL of A than grams of B per mL of B. So in this mixture, you have more grams of A then grams of B.
Now without even going to the next step mathematically, think about this conceptually. If you have more grams of A than grams of B, then compared to answer A, you will definitely have a higher mole fraction of A. In fact, you can change the two answer choices to this:
A. Mixture of 1.0 g of compound A and 1 g of compound B
B. mixture of more grams of compound A than grams of compound B.
If in answer choice A, there's an equal number of grams of A and B, and in answer choice B, there's more grams of A than grams of B, then which one will have the higher mole fraction?
Now, the molecular mass thing is a little confusing. I don't remember the other two choices off hand but I believe you need the molecular mass thing to eliminate the other choices.