I don’t know what you mean by solvation exception. But as an example, dissolving sodium hydroxide in water is an exothermic reaction. This means heat is released and is the product of the reaction. So by Le Chatelier’s principle, you would expect that decreasing the temperature would shift the reaction to the right and increase solubility of sodium hydroxide. However, solubility actually increases with increasing temperature.
An additional example of Le Chatelier's principle is the bicarbonate buffer facilitated by the respiratory system
Increasing pH would cause lower H+ concentration, therefore shifting reaction to right
Decreasing pH would cause higher higher H+ concentration, promoting respiration (release of CO2(g))
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