ECF is 20% of body weight.
Plasma is 1/4 of ECF.
Therefore:
Body Weight x .2 x 1/4 ~ Plasma weight
Plasma weight/ H20 density will roughly equal plasma volume.
Alternatively (and much more accurately):
Add a known quantity of Evans blue to the plasma. Allow to equibrilate.
V = amount added/final concentration
Source: My girl, Costanzo.